Section A
Q1.
(a)
The following results were obtained in the replicate determinations of Fe content in a mineral ore (in mg):
10.5, 10.6, 10.3, 10.6, 10.2, and 10.4.
Calculate the relative standard deviation (RSD) of this data.
(b) (i) What types of analyte can be separated by HPLC but not by GLC ?
(ii) What is the range of particle size used as stationary phase packing material in most packed GLC columns?
(c) What are the common sources suitable for infrared spectrometric analysis of an organic compound?
(d) What is the advantage and disadvantage of GF-AAS as compared to Flame-AAS ?
(e) How is temperature axis in thermogravimetry method calibrated ?
(f) How do K & L X-ray peaks of an element originate in XRF method ? Give a typical labelled wavelength dispersive XRF spectrum showing Kα & Kβ peaks of an element, e.g. Zn.
(g) How does high concentration of calcium interfere with ICP-MS analysis of iron ?
(h) What are the major constituents of type metal ? Suggest a method for non-destructive analysis of the constituents in type metal. (Description of the method is not required)