Q1.
(f)
What is 18-electron rule? Using the 18-electron rule predict the 'n' value for the following compounds :
(i) [u0006(C6H6) ext{Cr(CO)}_n]
(ii) [u0004(C4H4)_2 ext{ Mn}(Cl)(CO)_n]
(g) A wooden article of old age shows 40% as much ^{14}C activity as a fresh piece of wood. Calculate the age of the article. (t_{1/2} of ^{14}C = 5760 years)
(h) What is the usual order of preference of the alkali metal ions for a cation exchanging resin? Explain.
(i) Draw the structure of borazine. With the help of its reaction with HCl, explain why chemical properties of borazine are quite different from those of benzene.
(j) Atomic radii of two of the lanthanides are considerably higher than the other lanthanides. Identify those two lanthanides and explain the observation.