Section A
Q1.
(a) Define 'wet bulb' and 'dry bulb' temperatures. Dry mixture of HCl gas and air is passed over a heated catalyst, which promotes oxidation of acid. Air is used in 20% excess of that theoretically required. Calculate the weight of air supplied per kg of acid.
(b) A sample of limestone has CaCO3 (84% w/w), MgCO3 (12% w/w) and inert (4% w/w). Calculate the weight of CaO, obtained by 250 kg of sample limestone.
(c) Explain the need of equations of state for real gases, and discuss the limiting conditions that should be satisfied by an equation of state.
(d) For a reaction A ightarrow 4R, occurring in a variable volume batch reactor, derive the following expression: CA = CA0 (1 - XA)/(1 + \varepsilonA XA) ) where CA0 and CA are concentrations at t = 0 and time t; arepsilonA is fractional change in volume; XA is the conversion.
(e) What is degree of dissociation? A vessel has one mole N2O4 at 27 °C and one atmospheric pressure. The dissociation reaction takes place as N2O4 ightleftharpoons 2NO2. Calculate the degree of dissociation, if Kp for the above reaction is 0.