Section A
Q1.
(a)
The following values were obtained for the determination of cadmium in a sample of dust: 4.3, 4.1, 4.0 and 3.2 ,mu g ,g^{-1}
Applying the Q-test, decide whether the last value, 3.2, should be rejected or not. [Given : Q critical for a sample size of four is 0.831]
(b) What is the ultimate analysis of coal?
(c) A solution of concentration 1 × 10-3 M shows 60% transmittance where the cell thickness is 1 cm. Calculate the molar absorptivity of the sample solution. [Given : log10 (0.60) = -0.2218]
(d) How will you estimate Zn in brass gravimetrically?
(e) Mention the requisite conditions of the extracting solvent to be fit for solvent extraction.
(f) "Inductively Coupled Plasma (ICP) source is important as an atomisation source for emission spectroscopy." Explain why.
(g) Mention the function of Hollow Cathode Lamp (HCL). How does it function?
(h) "X-ray powder diffraction methods are well-suited for solid state qualitative identification." Explain why.