Q1.
(a) Calculate the de Broglie wavelength of an electron accelerated through a potential difference of 100 V. (Mass of electron = 9.109 imes 10^{-31} kg, charge of electron = 1.602 imes 10^{-19} C, Planck's constant = 6.626 imes 10^{-34} J s).
(b) Explain the concept of quantum defect and its significance in spectroscopy.
(c) Discuss the Born-Haber cycle and its application in calculating the lattice energy of ionic compounds.
(d) What is meant by the term 'thermodynamic stability'? Discuss the factors affecting the thermodynamic stability of a chemical compound.
(e) Explain the principle of spectroscopy and discuss the different types of spectroscopic techniques based on the interaction of electromagnetic radiation with matter.