Section A
Q1.
(a)
(i) Using the internationally accepted naming convention for ligands in an octahedral complex of an element Mn, what name would you give to the following? Br CO arphi2P-Mn-CO _{
m CO} Parphi arphi is Phenyl group
(ii) Predict the shape of ext{ICl}_4^- Z, Cl = 17 Z, I = 53
(b) What oxidant and fuel are generally used in a fuel cell ? Explain the working of Bacon fuel cell.
(c) Explain the effect of temperature on the distribution of molecular velocities.
(d) Deduce Nernst heat theorem and show that this forms the basis of third law of thermodynamics.
(e)
Derive Clapeyron equation applicable to sublimation process
logp1p2=-L2·303 R[1T1-1T2],
where L is the latent heat per gm-mole.
